The network dipole moment of CCl4 is zero because four C−Cl bond dipoles cancel every other. In the Chloromethane molecule (CH3Cl), chlorine is an ext electronegative than carbon, for this reason attracting the electrons in the C—Cl bond towards itself.
In CH3Cl, the result of 3C−H bond dipoles are reduced by one C-Cl shortcut dipole.
In CH2Cl, the resultant 2C−H bond dipoles are lessened by the resultant 2 C-Cl bond dipoles. Hence, the dipole minute of CH2Cl2 is reduced than the dipole minute of CH3Cl.Similarly, CHCl3 has a lower dipole moment than In CH2Cl2,The network dipole moment of CCl4 is zero because four C−Cl bond dipoles cancel every other.
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