Learning ObjectiveRecognize the chemical values of condensation reactions as they relate to polymerization.

You are watching: A dehydration reaction (or condensation reaction) is the process in which


Key PointsDuring condensation reaction, two molecules integrate to kind a solitary molecule v the ns of a little molecule; in dehydration reaction, this lost molecule is water.Intermolecular condensation occurs between two separate molecules, when intramolecular condensation is the union in between atoms or teams of the exact same molecule, frequently leading come ring formation.Condensation reactions are supplied in condensation polymerization, once a collection of condensation steps kind long chains; this reaction may be either a homopolymerization of a single monomer or a copolymerization of two co-monomers; many biological transformations room condensation reactions.
Termscondensation polymerizationa polymerization mechanism in which monomers react to type dimers first, then trimers, longer oligomers, and eventually lengthy chain polymerscondensation reactionany reaction in which 2 molecules react through the resulting loss that a water molecule (or other small molecule); the formal turning back of hydrolysisdehydration reactionan remove (condensation) reaction in i m sorry the tiny molecule that is eliminated is water

In a condensation reaction, two molecules or parts thereof combine, release a little molecule. As soon as this little molecule is water, it is known as a dehydration reaction. Other possible lost molecules incorporate hydrogen chloride, methanol, and acetic acid.

When two separate molecules react, their condensation is termed intermolecular. A an easy example is the condensation of two amino mountain to form a peptide. This reaction instance is the reverse of hydrolysis, which splits a chemistry entity into two components through activity from the polar water molecule, which chin splits right into hydroxide and hydrogen ions.

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Peptide shortcut formed throughout condensation reactionThe condensation (dehydration) of two amino mountain to form a peptide bond (red) through expulsion that water (blue).

When a condensation is performed between different parts of the exact same molecule, the reaction is termed intramolecular condensation; in plenty of cases, this leader to ring formation. An instance is the Dieckmann condensation, in i m sorry the 2 ester groups of a single diester molecule react with each various other to shed a little alcohol molecule and form a β-ketoester product.

Many condensation reactions monitor a nucleophilic acyl substitution or an aldol condensation reaction device (see previous concept for much more information). Various other condensations, such together the acyloin condensation, are prompted by radical conditions.

Condensation Polymerization Reactions

In one form of polymerization reaction, a series of condensation actions takes place through which monomers or monomer chains add to each other to type longer chains. This is termed “condensation polymerization,” or “step-growth polymerization,” and also occurs in such processes as the synthetic of polyesters or nylons. Nylon is a silky product used to make garments made that repeating units linked by amide bonds, and is frequently referred to as polyamide. This reaction might be either a homopolymerization that a solitary monomer A-B with two various end teams that condense, or a copolymerization of two co-monomers A-A and also B-B. Tiny molecules room usually liberated in these condensation steps, unequal polyaddition reactions.

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Condensation that diacid and also diamineThe condensation the a diacid and also diamine is an instance of A-B polymerization.

Condensation polymers often require heat, kind slower 보다 do enhancement polymers, and are lower in molecule weight. This form of reaction is provided as a basis for making countless important polymers, such as nylon, polyester, and various epoxies. The is likewise the basis for the laboratory development of silicates and polyphosphates. Many organic transformations, such as polypeptide synthesis, polyketide synthesis, terpene syntheses, phosphorylation, and glycosylations space condensations.

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Nylon molecule structureNylon is a fabricated polymer created by condensation polymerization.


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